7 September, 2016

K-Conjugated Dibenzoazahexacenes

Gabriella Antonicelli, Cristian Gozalvez, Ainhoa Atxabal, Manuel Melle-Franco, Luis E. Hueso, and Aurelio Mateo-Alonso.

Org. Lett., 2016, 18, 4694–4697
DOI: 10.1021/acs.orglett.6b02332

Full article: http://pubs.acs.org/doi/abs/10.1021/acs.orglett.6b02332


The synthesis and properties of two highly stable K-conjugated dibenzoazahexacenes are reported. Single-crystal X-ray, optoelectronic, and electrochemical characterization combined with theoretical studies show a favorable molecular packing and an optimal energy alignment of their frontier orbitals for charge transport. Electrical characterization illustrates that the preferential transport of holes or electrons depends on the number of N atoms in the aromatic framework.